愛媛大学工学部応用化学科 構造有機化学研究室

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論文

学会発表

受賞

2020年

原著論文

 

Donor-Acceptor Triads Composed of Tetrathiafulvalene and Benzoquinone Fused by Benzene-Spacers: the Application to the Positive Electrode Materials for Use in Rechargeable Batteries

Tomokazu Yamauchi, Wataru Hirabayashi, Aya Yoshimura, Masaru Yao, Yohji Misaki*

Bull. Chem. Soc. Jpn., Accepted for publication

 

Synthesis of Peripherally Arylated Tetrathiafulvalenes Extended with an Anthraquinoid Spacer via Pd-Catalyzed C−H Arylation and Construction of a Double-Helical Cobalt-Based Metal-Organic Framework

Aya Yoshimura, Keisuke Henmi, Hitoshi Kimura, Ryo Sakakibara, Rika Ochi, Takashi Shirahata, Hideki Yorimitsu , Yohji Misaki*

Synthesis, Accepted for publication

 

Synthesis and properties of tetrathiafulvalens bearing 6-aryl-1,4-dithiafulvenes

Aya Yoshimura, Hitoshi Kimura, Kohei Kagawa, Mayuka Yoshioka, Toshiki Itou, Dhananjayan Vasu, Takashi Shirahata, Hideki Yorimitsu, and Yohji Misaki

Beilstein J. Org. Chem. 2020, 16, 974-981.

 

Fused Tetrathiafulvalene and Benzoquinone Triads: Organic Positive Electrode Materials Based on Dual Redox System

Yohji Misaki* , Shigenobu Noda, Minami Kato, Tomokazu Yamauchi, Toko Oshima, Aya Yoshimura, Takashi Shirahata, Masaru Yao

ChemSusChem. 2020, 13, 2312-2320.

 

Synthesis, structures, and electrochemical and optical properties of λ5-phosphinine derivatives functionalized tetrathiafulvalene analogs

Aya Yoshimura, Hitoshi Kimura, Ayaka Handa, Naoki Hashimoto, Makoto Yano, Shigeki Mori, Takashi Shirahata, Minoru Hayashi,* Yohji Misaki*

Tetrahedron Lett. 2020, 14, 151724

総説・解説・著書


Catalytic C-H Arylation of Tetrathiafulvalenes for the Synthesis of Functional Materials

Hideki Yorimitsu, Aya Yoshimura, Yohji Misaki

Synthesis 2020, 52, 3326-3336 (Editor's choice)

Twiiterはこちら


2019年

原著論文

A Tris-Fused Donor System Composed of Two Tetrathiafulvalenes and an Extended Tetrathiafulvalene with an Anthraquinoid Spacer

Tomokazu Yamauchi, Minami Kato, Takashi Shirahata, Masaru Yao, Yohji Misaki*

Chem. Lett. 2019, 48, 1507-1510.

 

A molecular crystal with an unprecedentedly long-lived photoexcited state

Toshio Naito,*Naoki Watanabe, Yuuka Sakamoto, Yuuko Miyaji, Takashi Shirahata, Yohji Misaki, Shunsuke Kitou, and Hiroshi Sawa

Dalton Trans. 2019, 48, 12858-12866.

 

Structures and Conducting Properties of Molecular Conductors Based on Dimethyl-substituted ST-STP

Naoya Kinoshita, Takashi Shirahata,* and Yohji Misaki*

Chem. Lett. 2019, 48, 985-988.

 

Tris-fused Tetrathiafulvalenes Extended with an Anthraquinoid Spacer as New Positive Electrode Materials for Rechargeable Batteries

Daisuke Ogi, Yusuke Fujita, Minami Kato, Tomokazu Yamauchi, Takashi Shirahata, Masaru Yao, and Yohji Misaki*

Eur. J. Org. Chem. 2019, 2725-2728. (inside cover)

 

Hydration of Polycationic [5]Radialene with Quintuple 1,3-Dithiol-2-ylidenes Leads to a New Class of π-Extended Tetrathiafulvalene Scaffold

Masafumi Ueda, Akimi Tahara, Masashi Hasegawa, Takashi Shirahata,* Yasuhiro Mazaki, and Yohji Misaki*

Chem. Eur. J. 2019, 48, 4984-4991. (inside cover)

総説・解説・著書


Organic Rechargeable Batteries

Yohji Misaki

Functional Materials―Advances and Applications in Energy Storage and Conversion、Chapter 4、205-252, T. Naito Ed., Pan Stanford Publishing Pte. Ltd., Singapore(2019)


Development of Purely Organic Superconductors

Takashi Shirahata

Functional Materials―Advances and Applications in Energy Storage and Conversion、Chapter 5、253-323, T. Naito Ed., Pan Stanford Publishing Pte. Ltd., Singapore(2019)


1,3-ジチオール[n]ラジアレン類の合成と酸化還元特性

上田将史,御崎洋二*

有機合成化学協会誌 2019, 77, 1234-1246.

2018年

原著論文

Redox-Switchable Bis-fused Tetrathiafulvalene Analog: Observation and Control of Two Different Reduction Processes from Dication to Neutral State

Minami Kato, Yusuke Fujita, Tomokazu Yamauchi, Shigeki Mori, Takashi Shirahata,* and Yohji Misaki*

Org. Lett. 2018, 20, 5121-5125.

 

Structures and Conducting Properties of Molecular Conductors Based on DM-TTP

Naoya Kinoshita, Takashi Shirahata,* and Yohji Misaki*

Bull. Chem. Soc. Jpn. 2018, 10, 1553-1555.

 

Synthesis and Properties of [3]Dendralenes with Redox-active 1,3-Dithiol-2-ylidenes and Dicyanomethylidene and Application to Rechargeable Batteries

Tomokazu Yamauchi, Yuichi Shibata, Tatsuro Aki, Aya Yoshimura, Masaru Yao, and Yohji Misaki*

Chem. Lett. 2018, 47, 1176-1179.

 

Radical hydrophosphorylation of alkynes with R2P(O)H generating alkenylphosphine oxides: scope and limitations

Huang, Tianzeng; Saga, Yuta; Guo, Haiqing; Yoshimura, Aya; Ogawa, Akiya; Han, Li-Biao

J. Org. Chem. 2018, 83, 8743-8749.

 

Structures and Conducting Properties of Molecular Conductors Based on EO-ST-STP

Masaki Watanabe, Naoya Kinoshita, Takashi Shirahata, and Yohji Misaki*

Chem. Lett. 2018, 47, 982-984.

 

A Saddle-shaped Macrocycle Comprising 2,5-Diphenylthiophene Units

Tetsuo Iwanaga, Yuki Yamada, Tomokazu Yamauchi, Yohji Misaki, Masataka Inoue, and Haruo Yamada

Chem. Lett. 2018, 47, 760-762.

2017年

原著論文

A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

Aya Yoshimura, Michiyo Yoshinaga, Hiroshi Yamashita,* Masayasu Igarashi, Shigeru Shimada, and Kazuhiko Sato

Chem. Commun. 2017, 53, 5822-5825.

 

 

Crystal and Electronic Structures of [5]Radialene Substituted with Quintuple 1,3-Dithiol-2-ylidenes and Its Oxidative Species

Masafumi Ueda, Takashi Shirahata,* and Yohji Misaki*

ChemistrySelect. 2017, 2, 3490-3495.

 

 

Fused Donor-Donor-Acceptor Triads Composed of Tetrathiafulvalene and Benzoquinone Derivatives as the Positive Electrode Materials for Rechargeable Lithium and Sodium Batteries

Minami Kato, Shigenobu Noda, Tetsu Kiyobayashi, Masaru Yao, Yohji Misaki*

Chem. Lett. 2017, 46, 368-370.

2016年

原著論文

Molecular and Crystal Structures of Dicationic Tetrakis(1,3-benzodithiol-2-ylidene)cyclopentanone

Masafumi Ueda, Akimi Tahara, Takashi Shirahata,* and Yohji Misaki*

Bull. Chem. Soc. Jpn. 2016, 89, 1500-1502.

 

 

Bis- and Tris-fused Tetrathiafulvalenes Extended with Anthracene-9,10-diylidene

Daisuke Ogi, Yusuke Fujita, Shigeki Mori, Takashi Shirahata*, and Yohji Misaki*

Org. Lett. 2016, 18, 5868-5871.

 

 

Metal−Insulator Transition of the New One-Dimensional Organic Conductors with Complete Uniform Stacks: (DMEDO-TTF)2X (X = ClO4 and BF4)

Shohei Kumeta, Tadashi Kawamoto, Takashi Shirahata, Yohji Misaki, and Takehiko Mori
J. Phys. Soc. Jpn. 2016, 85, 094701-1-7.

 

 

Synthesis, Structure, Optical, and Electrochemical Properties of Triple- and Quadruple-decker Co-facial Tetrathiafulvalene Arrays

Masashi Hasegawa, Ken-ichi Nakamura, Saki Tokunaga, Yumi Baba, Ryota Shiba, Takashi Shirahata, Yasuhiro Mazaki , Yohji Misaki
Chem. Eur. J. 2016, 22, 10090-10101.



Vilsmeier-Haack Type Formylation on 6-Aryl-1,4-dithiafulvenes and Syntheses of Novel Extended Tetrathiafulvalene Donors

Atsushi Fujioka, Takashi Kubo, Miho Watanabe, Masafumi Ueda, Hisakazu Miyamoto, Yohji Misaki
Synthesis 2016, 48, 845-854.

総説・解説・著書


有機材料を用いた次世代蓄電池の創成, 御崎洋二, ケミカルエンジニアリング, 61(3), 175-180 (2016).
2015年

New Tris- and Pentakis-Fused Donors Containing Extended Tetrathiafulvalenes: New Positive Electrode Materials for Rechargeable Batteries

Shintaro Iwamoto, Yuu Inatomi, Daisuke Ogi, Satoshi Shibayama, Yukiko Murakami, Minami Kato, Kazuyuki Takahashi, Kazuyoshi Tanaka, Nobuhiko Hojo and Yohji Misaki
Beilstein J. Org. Chem., 11, 1136-1092 (2015).

Synthesis of New Electron Donor ClMe3-TTP: Structures and Properties of (ClMe3-TTP)3X
(X = PF6 and AsF6)

Takashi Shirahata, Shuhei Kohno, Keisuke Furuta, Yusuke Oka, and Yohji Misaki
Bull. Chem. Soc. Jpn., 88, 1086-1092 (2015).

Synthesis and Properties of Fused π-Electron Donors Possessing Vinylogous 1, 3-Dithiole
[5]Radialene Units

Takashi Matsuda, Masafumi Ueda, Rina Kondo, Mizuka Suwaki, and Yohji Misaki
Bull. Chem. Soc. Jpn., 88, 850-856 (2015).

Synthesis, Structures, and Electrochemical Properties of New Extensively Conjugated TTF

Daisuke Ogi, Shuka Yoshimoto, Takashi Shirahata, and Yohji Misaki
Chem. Lett., 44, 554-556 (2015).
2014年

Molecular Conductors with Effectively Half-Filled Electronic States Based on TTF Derivatives Condensed with a 2-Isopropylidene-1,3-dithiole Ring

Keisuke Furuta, Shuhei Kohno, Takashi Shirahata, and Yohji Misaki
Eur. J. Inorg. Chem. 2014, 3982-3988 (2014).

Stable metallic state of (TTPCOO)2NH4 with mobile dopant

Takeshi Terauchi, Satoshi Sumi, Yaka Kobayashi, Toshikazu Nakamura, Ko Furukawa, and Yohji Misaki
Chem. Commun. 50 , 7111-7113 (2014).

Dendritic Tetrathiafulvalene Pentamers Linked by Methylenedithio Spacers

Haruka Kimura, Katsuya Konishi, Shun-ya Muraoka, Takashi Shirahata, and Yohji Misaki
Chem. Lett., 43, 843−845 (2014).

A pentakis-fused tetrathiafulvalene system extended by cyclohexene-1,4-diylidenes: a new positive electrode material for rechargeable batteries utilizing ten electron redox

M. Kato, K. Senoo, M. Yao, and Y. Misaki
J. Mater. Chem. A, 2, 6747−6754 (2014).

Cyclic TTF Tetramer Linked by Methylenedithio Spacers

Ken-ichi Nakamura, Yuuki Okada, Takashi Shirahata, and Yohji Misaki
Chem. Lett., 43, 708−710 (2014).
2013年

A Tris-fused Tetrathiafulvalene Extended with Cyclohexene-1,4-diylidene:A New Positive Electrode Material Organic Rechargeable Batteries

M. Kato, T. Shirahata and Y. Misaki
Chem. Lett., 42, 1556−1558 (2013).

A New Bis-fused π-Electron Donor Composed of Tetrathiafulvalene and 2-(Xanthen-9-ylidene)-1,3-dithiole

M. Kato, T. Shirahata and Y. Misaki
Chem. Lett., 42, 1548−1550 (2013).

[5]Radialene-Fused Tetrathiafulvalenes Exhibiting a Simultaneous Four- or Eight-Electron Transfer

M. Ueda, and Y. Misaki
Org. Lett.,15, 3824-3827 (2013).

Oxidation States of [5]Radialene with Five 1,3-Dithiol-2-ylidenes and Its Oxygen Adduct

M. Ueda, T. Shirahata, Y. Misaki
Chem. Lett., 42, 565−567 (2013).

Synthesis and Properties of Novel [5]Radialenes Substituted with Multiple 1,3-Dithiol-2-yildenes

M. Ueda, Y. Ogura, Y. Misaki
Chem. Lett., 42, 562−564 (2013).
2012年

Synthesis and Properties of 2-Alkylidene-1,3-dithiolo [4,5-d]-4,5-ethylenediselenotetrathiafulvalene Derivatives and Crystal Structures of Their Cation Radical Salts

K. Furuta, S. Kohno, T. Shirahata, K. Yamasaki, S. Hino, Y. Misaki
Crystals, 2, 393−412 (2012).

Construction of a rechargeable battery using multifused tetrathiafulvalene systems as cathode materials.

Y. Inatomi, N. Hojo, T. Yamamoto, S. Watanabe, and Y. Misaki
ChemPulsChem, 77, 973-976 (2012).

Structural transitions from triangular to square molecular arrangements in the quasi-one-dimensional molecular conductors (DMEDO-TTF)2XF6(X = P, As, and Sb).

T. Shirahata, K. Shiratori, S. Kumeta, T. Kawamoto, T. Ishikawa, S. Koshihara, Y. Nakano, H. Yamochi, Y. Misaki and T. Mori
J. Am. Chem. Soc., 134, 13330-13340 (2012).

Synthesis, structure and properties of molecular conductors based on bis-fused donors composed of (thio)pyran-4-ylidende-1,3-dithiole and tetraselenafulvalene.

K. Ishidzu, M. Ashizawa, M. Watanabe, T. Shirahata, and Y. Misaki
Crystals, 2, 1092-1107 (2012).

Synthesis and properties of tris-fused tetrathiafulvalene analogues possessing [3]dendralene moieties.

Y. Kajiwara, S. Hino, and Y. Misaki
Bull. Chem.Soc.Jpn., 85, 830-835 (2012).

Synthesis of bis-fused tetrathiafulvalene with mono- and dicarboxylic acids.

T. Terauchi, Y. Kobayashi, and Y. Misaki
Tetrahedron Lett., 53, 3277-3280 (2012).

Probing the metal-insulator phase transition in the (DMEDO-EBDT)2PF6 single crystal by optical measurements.

T. Ishikawa, M. Kitayama, A. Chono, K. Onda, Y. Okimoto, S. Koshihara, Y. Nakano, H. Yamochi, T. Morikawa, T. Shirahata, and Y. Misaki
J. Phys.: Condens. Matter, 24, 195501-1−9 (2012).

Structures and electrical properties of a new molecular conductor, (BSM-TTP)4(PF6)3(C6H5Cl)2.

H. Tsuji, M. Yasuda, T. Shirahata, H. Fujiwara, T. Sugimoto, and Y. Misaki
Phys. Status Solidi C, 9, 1149−1151 (2012).

Synthesis of a new donor, MOET-TTP, and the crystal structure, electrical, and magnetic properties of (MOET-TTP)2MCl4 (M = Fe and Ga)

T. Shirahata, T. Ito, S. Toki, and Y. Misaki
Phys. Status Solidi B, 249, 929−932 (2012).
2011年

Synthesis and Properties of New Trimeric and Tetrameric TTF with Alternative-sided Links.

K. Nakamura, T. Hashimoto, T. Shirahata, S. Hino, M. Hasegawa, Y. Mazaki, and Y. Misaki
Chem. Lett., 40, 883-885 (2011).

SYNTHESIS AND PROPERTIES OF A NEW DONOR-ACCEPTOR DIAD COMPOSED OF DT-TTF AND DICYANOMETHYLIDENE GROUP.

K. Nakamura, T. Shirahata, H. Miyamoto, and Y. Misaki
Heterocycles, 83, 2115-2126 (2011).

Dimeric and Trimeric Tetrathiafulvalenes with Strong Intramolecular Interactions in the Oxidized States.

K. Nakamura, T. Takashima, T. Shirahata, S. Hino, M. Hasegawa, Y. Mazaki, and Y. Misaki
Org. Lett., 12, 3122-3125 (2011).

Synthesis and Properties of 1,3-Dithiole[4]dendralenes, in Which Two Thiophene Rings Are Inserted.

M. Nishiwaki, M. tezuka, T. Shirahata, and Y. Misaki
Chem. Lett., 40, 467-469 (2011).

Novel Molcular Conductors Based on Cyclopenteno- TTP Showing Strong Self-aggregation.

M. Nishiwaki, K. Nakamura, T. Shirahata, and Y. Misaki
Chem. Lett., 40, 452-454 (2011).

New Molecular Metals Based on a Tetrathiapentalene Donor with Peripheral Methoxy Groups.

T. Ito, K. Nakamura, T. Shirahata, T. Kawamoto, T. Mori, and Y. Misaki
Chem. Lett., 40, 81-83 (2011).

Structures and Electrical Properties of (BTM-TS-TTP)4PF6.

M. Yasuda, E. Fujiwara, S. Aonuma, H. Fujiwara, T. Sugimoto, T. Nakayashiki, K. Tanaka, K. Takahashi, H. Kobayashi, and Y. Misaki
Bull. Chem. Soc. Jpn., 84, 79-81 (2011).
2010年

Novel Bis-fused π-Electron Donor Composed of Tetrathiafulvalene and Tetraselenafulvalene.

M. Ashizawa, K. Ishidzu, M. Watanabe, T. Tanahashi, T. Shirahata, T. Kawamoto, T. Mori, and Y. Misaki
Chem. Lett., 39, 1093-1095 (2010).

Synthesis and Properties of 1,3-Dithiole[5]dendralenes with Two Thiophene Spacers.

H. Horiuchi, and Y. Misaki
Chem. Lett., 39. 989-991 (2010).

Charge disproportionation in a semiconducting θ-type salt of BTM-TTP.

Y. Nakano, M. Uruichi, K. Yakushi, H. Yamochi, and Y. Misaki
Physica B., 405. S198-S201 (2010).

Syntheses, structure and properties of vinylogous EDO-TTFs

T. Shirahata, T. Morikawa, H. Miyamoto, Y. Nakano, H. Yamochi, and Y. Misaki
Physica B., 405. 61-64 (2010).
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