愛媛大学工学部応用化学科　構造有機化学研究室

論文


Synthesis and Properties of [3]Dendralenes with Redox-active 1,3-Dithiol-2-ylidenes and Dicyanomethylidene and Application to Rechargeable Batteries Tomokazu Yamauchi, Yuichi Shibata, Tatsuro Aki, Aya Yoshimura, Masaru Yao, and Yohji Misaki* Chem. Lett., 2018, Accepted for publication.
Structures and Conducting Properties of Molecular Conductors Based on EO-ST-STP Masaki Watanabe, Naoya Kinoshita, Takashi Shirahata, and Yohji Misaki* Chem. Lett., 2018, in press.
A pentakis-fused tetrathiafulvalene system extended by cyclohexene-1,4-diylidenes: a new positive electrode material for rechargeable batteries utilizing ten electron redox M. Kato, K. Senoo, M. Yao, and Y. Misaki J. Mater. Chem. A, 2, 6747－6754 (2014).
[5]Radialene-Fused Tetrathiafulvalenes Exhibiting a Simultaneous Four- or Eight-Electron Transfer M. Ueda, and Y. Misaki Org. Lett., , (2013).
Oxidation States of [5]Radialene with Five 1,3-Dithiol-2-ylidenes and Its Oxygen Adduct M. Ueda, T. Shirahata, Y. Misaki Chem. Lett., 42, 565－567 (2013).
Synthesis and Properties of Novel [5]Radialenes Substituted with Multiple 1,3-Dithiol-2-yildenes M. Ueda, Y. Ogura, Y. Misaki Chem. Lett., 42, 562－564 (2013).
Synthesis and Properties of 2-Alkylidene-1,3-dithiolo [4,5-d]-4,5-ethylenediselenotetrathiafulvalene Derivatives and Crystal Structures of Their Cation Radical Salts K. Furuta, S. Kohno, T. Shirahata, K. Yamasaki, S. Hino, Y. Misaki Crystals, 2, 393－412 (2012).
Construction of a rechargeable battery using multifused tetrathiafulvalene systems as cathode materials. Y. Inatomi, N. Hojo, T. Yamamoto, S. Watanabe, and Y. Misaki ChemPulsChem, 77, 973-976 (2012).
Structural transitions from triangular to square molecular arrangements in the quasi-one-dimensional molecular conductors (DMESO-TTF)₂XF₆(X = P, As, and Sb). T. Shirahata, K. Shiratori, S. Kumeta, T. Kawamoto, T. Ishikawa, S. Koshihara, Y. Nakano, H. Yamochi, Y. Misaki and T. Mori J. Am. Chem. Soc., 134, 13330-13340 (2012).
Synthesis, structure and properties of molecular conductors based on bis-fused donors composed of (thio)pyran-4-ylidende-1,3-dithiole and tetraselenafulvalene. K. Ishidzu, M. Ashizawa, M. Watanabe, T. Shirahata, and Y. Misaki Crystals, 2, 1092-1107 (2012).
Synthesis and Properties of New Trimeric and Tetrameric TTF with Alternative-sided Links. K. Nakamura, T. Hashimoto, T. Shirahata, S. Hino, M. Hasegawa, Y. Mazaki, and Y. Misaki Chem. Lett., 40, 883-885 (2011).
SYNTHESIS AND PROPERTIES OF A NEW DONOR-ACCEPTOR DIAD COMPOSED OF DT-TTF AND DICYANOMETHYLIDENE GROUP. K. Nakamura, T. Shirahata, H. Miyamoto, and Y. Misaki Heterocycles, 83, 2115-2126 (2011).
Dimeric and Trimeric Tetrathiafulvalenes with Strong Intramolecular Interactions in the Oxidized States. K. Nakamura, T. Takashima, T. Shirahata, S. Hino, M. Hasegawa, Y. Mazaki, and Y. Misaki Org. Lett., 12, 3122-3125 (2011).
Synthesis and Properties of 1,3-Dithiole[4]dendralenes, in Which Two Thiophene Rings Are Inserted. M. Nishiwaki, M. tezuka, T. Shirahata, and Y. Misaki Chem. Lett., 40, 467-469 (2011).
Novel Molcular Conductors Based on Cyclopenteno- TTP Showing Strong Self-aggregation. M. Nishiwaki, K. Nakamura, T. Shirahata, and Y. Misaki Chem. Lett., 40, 452-454 (2011).
New Molecular Metals Based on a Tetrathiapentalene Donor with Peripheral Methoxy Groups. T. Ito, K. Nakamura, T. Shirahata, T. Kawamoto, T. Mori, and Y. Misaki Chem. Lett., 40, 81-83 (2011).
Structures and Electrical Properties of (BTM-TS-TTP)₄PF₆. M. Yasuda, E. Fujiwara, S. Aonuma, H. Fujiwara, T. Sugimoto, T. Nakayashiki, K. Tanaka, K. Takahashi, H. Kobayashi, and Y. Misaki Bull. Chem. Soc. Jpn., 84, 79-81 (2011).
Novel Bis-fused π-Electron Donor Composed of Tetrathiafulvalene and Tetraselenafulvalene. M. Ashizawa, K. Ishidzu, M. Watanabe, T. Tanahashi, T. Shirahata, T. Kawamoto, T. Mori, and Y. Misaki Chem. Lett., 39, 1093-1095 (2010).
Synthesis and Properties of 1,3-Dithiole[5]dendralenes with Two Thiophene Spacers. H. Horiuchi, and Y. Misaki Chem. Lett., 39. 989-991 (2010).
Syntheses, structure and properties of vinylogous EDO-TTFs T. Shirahata, T. Morikawa, H. Miyamoto, Y. Nakano, H. Yamochi, and Y. Misaki Physica B., 405. 61-64 (2010).
Charge disproportionation in a semiconducting θ-type salt of BTM-TTP. Y. Nakano, Y. Misaki, M. Uruichi, K. Yakushi, H. Yamochi Physica B., 405. 198-201 (2010).
Synthesis and properties of new TTP donors composed of TTF and TSF moieties. K. Ishizu, M. Watanabe, T. Tanahashi, Y. Misaki, M. Ashizawa, and T. Mori J. Phys: Conf. Ser., 132, 012021(5pp) (2008).
Synthesis and Properties of Dimeric Donors Composed of TTF and BDT-TTP. Y. Misaki, T. Yamanaka, Y. Murakami, H. Fueno, and K. Tanaka J. Phys: Conf. Ser., 132, 012022(6pp) (2008).
Modulating the Framework Negative Charge Density in the System [BDT-TTP^・+]/[Re₆S₅Cl₉^1-]/[Re₆(S/Se)₆Cl₈^2-]/[Re₆S₇Cl₇^3-]: Templating by Isosteric Cluster Anions of Identical Symmetry and Shape, Variations of Incommensulate Band Filling, and Electronic Structure in 2D Metals. S. Perruchas, K. Boubekeur, E. Canadell, Y. Misaki, P. Auban-Senzier, C. Pasquier, and P. Batail J. Am. Chem. Soc., 130, 3335-3348 (2008).
Syntheses and Properties of Thiophene-inserted [3]Dendralenes with Redox-active 1,3-Dithiol-2-ylidene Units. M. Hasegawa, A. Fujioka, T. Kubo, T. Honda, H. Miyamoto, and Y. Misaki Chem. Lett., 37，474-475 (2008).
Structures and Electrical Properties of β- and θ-(BTM-TTP)c. M. Noda, M. Yasuda, Y. Nakano, A. Ito, H. Fueno, K. Tanaka, H. Fujiwara, T. Sugimoto, and Y. Misaki Chem. Lett., 37, 396-397 (2008).
New π-Electron Donors with a 2,2,5,5-Tetramethylpyrrolin-1-yloxyl Radical Designed for Magnetic Molecular Conductors. E. Fujiwara, S. Aonuma, H. Fujiwara, T. Sugimoto, and Y. Misaki Chem. Lett., 37, 84-85 (2008).
Synthesis and Properties of New Tetrathiapentalene Donors Composed of Vinylogous TTFs. S. Iwamoto, S. Watanabe, H. Fueno, K. Tanaka, and Y. Misaki Chem. Lett., 37, 82-83 (2008).
Synthesis and Properties of DT-TTF Derivatives Possessing Dicyanomethyene Group as the Acceptor Unit. S. Matsumoto, M. Hayashi, H. Fueno, K. Tanaka, H. Miyamoto, and Y. Misaki Multifunctional Conducting Molecular Materials, G. Saito, F. Wudl, R. C. Haddon, K. Tanigaki eds., RSC Publishing, 75-78 (2007).
Structures and Electrical Properties of New PDT-TTP Conductors. M. Daini, Y. Misaki, K. Tanaka, Multifunctional Conducting Molecular Materials, G. Saito, F. Wudl, R. C. Haddon, K. Tanigaki eds., RSC Publishing, 127-130 (2007).
Synthesis and Properties of Oligocarboxamide Molecular Strands Containing 1,8-Naphthyridine and Pyridine Groups. H. Miyamoto, T. Ikeuchi, A. Fujioka, J-M. Lehn, S. Ohba, and Y. Misaki Heterocycles, 68, 2023-2029 (2006).
Structures and Electrical Properties of Molecular Conductors Based on Bis-Fused TTF Donors with Bis(alkylthio) Groups. M. Noda, Y. Misaki, and K. Tanaka Curr. Apply. Phys., 6, 943-937 (2006).
Synthesis and properties of higher homologs of extended TTP donors. Y. Misaki, A. Kubo, W. Matsuda, H. Fueno, and K. Tanaka Curr. Apply. Phys., 6, 934-938 (2006).
Synthesis and Properties of TTF Oligomers Possessing Electron-Withdrawing Groups in the Spacer. S. Matsumoto, W. Matsuda, H. Fueno, Y. Misaki, and K. Tanaka Synth. Met., 153, 429-432 (2005).
Synthesis and Structures of Highly Conducting Charge-Transfer Salts of Selenium Containing TTM-TTP Derivatives. M. Ashizawa, A. Akutsu, B. Noda, H. Nii, T. Kawamoto, T. Mori, T. Nakayashiki, Y. Misaki, K. Tanaka, K. Takimiya, and T. Otsubo Bull. Chem. Soc. Jpn., 77, 1449-1458 (2004).
Conducting Properties of Tris-Fused Tetrathiafulvalenes. T. Mori, M. Ashizawa, S. Kimura, A. Akutsu-Sato, B. Noda, Y. Misaki, and K. Tanaka J. Phys. IV France, 114, 549-551 (2004).
Tris-Fused Tetrathiafulvalenes (TTF): Highly Conducting Single-Component Organics and Metallic Charge-Transfer Salt. M. Ashizawa, S. Kimura, T. Mori, Y. Misaki, and K. Tanaka Synth. Met., 141, 307-313 (2004).
Molecular Paramagnetic Semiconductor: Crystal Structures and Magnetic and Conducting Properties of the Ni(dmit)2 Salts of 6-Oxoverdazyl Radical Cations (dmit = 1,3-Dithiol-2-thione-4,5-dithiolate). K. Mukai, N. Senba, H. Hatanaka, H. Minakuchi, K. Ohara, M. Taniguchi, Y. Misaki, Y. Hosokoshi, K. Inoue, N. Azuma Inorg. Chem., 43, 566-576 (2004).
Synthesis and Structures of Neutral Crystals and Charge-Transfer Salts of Selenium Containing TMET-TTP Derivatives. M. Ashizawa, H. Nii, T. Mori, Y. Misaki, K. Tanaka, K. Takimiya, and T. Otsubo Bull. Chem. Soc. Jpn., 76, 2091-2097 (2003).
Structural, Electrical, and Magnetic Properties of a Series of Molecular Conductors Based on BDT-TTP and Lanthanoid Nitrate Complex Anions (BDT-TTP = 2,5-Bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene). H. Cui, T. Otsuka, A. Kobayashi, N. Takeda, M. Ishikawa, Y. Misaki, and H. Kobayashi Inorg. Chem., 42, 6114-6122 (2003).
Genuine Organic Magnetic Semiconductors: Electrical and Magnetic Properties of the TCNQ and Iodine Salts of Methylpyridinium-Substituted Verdazyl Radicals. K. Mukai, S. Jinnno, Y. Shimobe, N. Azuma, M. Taniguchi, Y. Misaki, K. Tanaka,K. Inoue, and Y. Hosokoshi J. Mater. Chem., 13, 1614-1621 (2003).
Synthesis and Properties of Dimeric BDT-TTP Derivatives. Y. Misaki, K. Takahashi, S. Watanabe, H. Fueno, and K. Tanaka Synth. Met., 137, 937-938 (2003).
Synthesis and Properties of π-Extended Donors with Crown Ether Units. K. Sako, H. Oku, Y. Misaki, K. Tanaka, and H. Tatemitsu Synth. Met., 137, 901-902 (2003).
Synthesis and Properties of New Extended TTP Analogs. Y. Misaki, Y. Natsume, K. Takahashi, H. Fueno, and K. Tanaka Synth. Met., 135-136, 671-672 (2003).
Structure and Properties of SMEO-ST-TTP Salts. Y. Misaki, T. Nakayashiki, S. Yoshida, K. Tanaka and T. Mori Synth. Met., 135-136, 669-670 (2003).
Syntheses and Physical Properties of New Organic Conductors with Lanthanoid Chloride Complex Anions. H. B. Cui, T. Otsuka, E. Fujiwara, A. Kobayashi, Y. Misaki, and H. Kobayashi Synth. Met., 135-136, 641-642 (2003).
Synthesis and Properties of Selenium Containing TTM-TTP Conductors. M. Ashizawa, H. Nii, T. Kawamoto, T. Mori, Y. Misaki, K. Tanaka, K. Takimiya, and T. Otsubo Synth. Met., 135-136, 627-628 (2003).
Charge Disproportionation in the Charge-Transfer Salts of TTP. K. Yakushi, R. Swietlik, K. Yamamoto, T. Kawamoto, T. Mori, Y. Misaki, and K. Tanaka Synth. Met., 135-136, 583-585 (2003).
Magnetic Investigation of Itinerant and Local Hybrid Spins System, (CHTM-TTP)₂TCNQ T. Nakamura, M. Taniguchi, Y. Misaki, K. Tanaka, and Y. Nogami Synth. Met., 133-134, 441-442 (2003).
Charge Ordering and Phase Transition in θ-(BDT-TTP)₂Cu(NCS)₂. K. Yakushi, K. Yamamoto, J. Ouyang, M. Simonyan, C. Nakano, Y. Misaki, and K. Tanaka Synth. Met., 133-134, 287-289 (2003).
Structural and Electrical Properties of Novel Molecular Conductors Based on Extended-TTF Donors BDT-TTP and I- Anions. H-B. Cui, T. Otsuka, A. Kobayashi, Y. Misaki, and H. Kobayashi Bull. Chem. Soc. Jpn., 76, 97-102 (2003).
Charge-ordering and Magnetic Phase Transition in θ-(BDT-TTP)₂Cu(NCS)₂. K. Yakushi, K. Yamamoto, M. Simonyan, J. Ouyang, C. Nakano, Y. Misaki, and K. Tanaka Phys. Rev. B., 66, 235102(5pp) (2002).
Metal-Semiconductor Transition of the New Organic Conductor (DTEDT)₃Ag(CN)₂. T. Kawamoto, T. Mori, J. Yamaura, and Y. Misaki J. Phys. Soc. Jpn., 71, 2975-2979 (2002).
Structures and Transport Properties of New Molecular Conductors Based on TMEO-ST-TTP. Y. Misaki, M. Taniguchi, K. Tanaka, K. Takimiya, A. Morikami, T. Otsubo, and T. Mori J. Solid State Chem., 168, 608-615 (2002).
Optical Study of Two-Dimensional Organic Metal (EO-TTP)₂AsF₆ (EO-TTP = 2-(4,5-Ethylenedioxy-1,3-Dithiol-2-Ylidene)-5-(1,3-Dithiol-2-Ylidene)-1,3,4,6-Tetrathiapentalene). O. Drozdova, K. Yakushi, Y. Misaki, and K. Tanaka J. Solid State Chem., 168, 497-502 (2002).
Magnetism of Metallic Molecular Crystals with Rare-Earth Complex Anions. T. Otsuka, H.-B. Cui, A. Kobayashi, Y. Misaki, and H. Kobayashi J. Solid State Chem., 168, 444-449 (2002).
Magnetic Semiconductor: Structural, Magnetic, and Conducting Properties of the Salts of the 6-Oxoverdazyl Radical Cation with M(dmit)₂ Anions (M = Ni, Zn, Pd and Pt, dmit = 1,3-dithiol-2-thione-4,5-dithiolate). K. Mukai, T. Hatanaka, N. Senba, T. Nakayashiki, Y. Misaki, K. Tanaka, K. Ueda, T. Sugimoto, and N. Azuma Inorg. Chem., 41, 5066-5074 (2002).